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which for GaAs gives, 203,000 atoms. This seems like quite a large number and hence provides justification for using the bulk value of the permittivity er. For systems with a much smaller Bohr radius, which might contain substantially fewer atoms, it would be apparent that the electromagnetic properties of the crystal are quite different from the bulk and care must be taken in choosing the value for the permittivity. A recent work [102], has shown by careful comparison of exciton binding calculations with detailed experimental work, that the permittivity required to produce agreement lies between the static, es, and infinite, e00, frequency values. The binding energies themselves are small relative to the bandgap and, obviously, negative, which implies that they lie just below the conduction-band edge. At low temperatures, there are few lattice vibrations (phonons) and hence the electrons remain bound to the donors. However, as the temperature is increased the number of phonons within the lattice increases and the donors can become ionised, thus liberating electrons into the conduction band of the crystal. The occupancy (proportion of ionised donors) can be represented by statistics [1,2], but this is not of particular concern here as most experiments are performed at liquid helium temperatures where all of the donors can be considered occupied, or at room temperature where they can be considered ionised.

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[Hussain et al 1997] A Hussain, JJ Soraghan, TS Durban!, A New Neural Network for Nonlinear Time-Series Modelling, NeuroVest Journal, Jan 1997, pp 16 26 [Hwang et al 1991] J-N Hwang, JJ Choi, S Oh, RJ Marks II, Query-Based Learning Applied to Partially Trained Multilayer Perceptrons, IEEE Transactions on Neural Networks, Vol 2, No 1, 1991, pp 131 136 [Ismail and Engelbrecht 2002] A Ismail, AP Engelbrecht, Improved Product Unit Neural Networks, IEEE World Congress Computational Intelligence, Proceedings of the International Joint Conference on Neural Networks, Honolulu, Hawaii, 2002 [Jacobs 1988] RA Jacobs, Increased Rates of Convergence Through Learning Rate Adaption, Neural Networks, Vol 1, No 4, 1988, pp 295 308.

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In order to illustrate the summation rules, we recall a well-known legend. According to the legend, when he was just nine years old, the famous mathematician Karl Friedrich Gauss was told to add all the numbers from 1 to 100 by his teacher. The teacher wanted to keep Gauss occupied for some time, but Gauss foiled him by simply writing down

At first sight, the direct analogy of acceptors in p-type material would appear to be described by the above equations, but with the hole mass replacing the electron mass and the binding energy now referring to a hole bound to a negatively charged acceptor. The hydrogenic model for a hole bound to an acceptor would give

Taking the typical values for GaAs of mhh=0.62 mo and er=13.18 again, then:

1 + 2 + + 100 ,

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[Janikow and Michalewicz 1991] CZ Janikow, Z Michalewicz, An Experimental Comparison of Binary and Floating Point Representations in Genetic Algorithms, in RK Belew, LB Booker (eds), Proceedings of the 4th International Conference in Genetic Algorithms, Morgan Kaufmann, 1991, pp 31 36 [Janson and Frenzel 1993] DJ Janson, JF Frenzel, Training Product Unit Neural Networks with Genetic Algorithms, IEEE Expert, Oct 1993, pp 26 33 [Jantzen 1998] J Jantzen, Design of Fuzzy Controllers, Technical Report 98-E864, Department of Automation, Technical University of Denmark, 1998 [Kamruzzaman et al 1992] J Kamruzzaman, Y Kumagai, H Hikita, Study on Minimal Net Size, Convergence Behavior and Generalization Ability of Heterogeneous Backpropagation Network, in I Aleksander, J Taylor (eds), Artificial Neural Networks, Vol 2, 1992, pp 203 206.

Unlike the donor case, this doesn't agree well with experimentally measured values [44] In fact, in practice the acceptor state is much more complex for a number of reasons First, often the valence band at the F minimum consists of two degenerate states (the light- and heavy-holes), and thus it is not clear which effective mass should be employed, or indeed whether the hole is a mixture of both light- and heavy-hole states Although, however, this degeneracy is usually broken within a quantum well, due to the differing effect of the confining potential on the effective masses Secondly, the much larger heavy-hole mass has the effect of producing a much smaller Bohr radius A, ie the hole orbits much more closely to the central Coulombic potential, as can be seen from the calculated radius above.

He then proceeded to add the two rows together:

Consequently the approximation that the bulk relative permittivity e describes the electromagnetic response of the lattice is questionable, although a technique for accounting for this problem will be introduced later, in Section 56 The problem of point defects will be revisited much later in 11 and dealt with by a microscopic model which will take these effects into account For now concentration will be focused on donors 52 BINDING ENERGY IN A HETEROSTRUCTURE When a donor is placed within a quantum well structure, the situation is considerably more complex than in the bulk, due to two additional degrees of freedom First, the binding energy depends upon the confining potential due to the quantum well structure In its simplest form this would be the well width, schematically represented in Fig 52 Beyond this, however, lies the possibility of a more complex heterostructure.

101 + 101 + + 101 ,

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